This test with a ControlTemplate I had copied from the doc works for me :
<ControlTemplate x:Key="RoundButton" TargetType="Button">
<Grid>
<VisualStateManager.VisualStateGroups>
<VisualStateGroup x:Name="CommonStates">
<VisualState x:Name="Normal">
<Storyboard>
<ColorAnimation Storyboard.TargetName="backgroundElement"
Storyboard.TargetProperty="(Shape.Fill).(SolidColorBrush.Color)"
To="{TemplateBinding Background}"
Duration="0:0:0.3"/>
</Storyboard>
</VisualState>
<VisualState x:Name="PointerOver">
<Storyboard>
<ColorAnimation Storyboard.TargetName="backgroundElement"
Storyboard.TargetProperty="(Shape.Fill).(SolidColorBrush.Color)"
To="Yellow"
Duration="0:0:0.3"/>
</Storyboard>
</VisualState>
</VisualStateGroup>
</VisualStateManager.VisualStateGroups>
<Ellipse x:Name="backgroundElement" Fill="{TemplateBinding Background}" Stroke="{TemplateBinding Foreground}" />
<ContentPresenter HorizontalAlignment="Center" VerticalAlignment="Center" />
</Grid>
</ControlTemplate>
Then :
<Button Template="{StaticResource RoundButton}" Width="100" Height=" 32" >Test Button</Button>
Test :