Why do you want to deploy the hybrid?
Do you have any mailboxes on on-premises Exchange?
For your questions:
- Are these two connectors created on Exchange Online, and used to send emails from different SMTP address?
HCW helps to create connectors for mail flow between on-premises Exchange and Exchange Online. If your connectors are created on Exchange Online and no on-premises mailboxes use bbb.com or ccc.com, your connectors won't be affected.
2) The url you provided "https://exchangeserver.aaa.org/Autodiscover/Autodiscover.xml" looks like the SCP record, am I right?
If you have on-premises mailboxes, yes, you should make autodiscover.aaa.org pointed to the public IP of your on-premises Exchange server.
If you don't have on-premises mailboxes, you should create the CNAME record to make autodiscover.aaa.org points to autodiscover.outlook.com. Also, you should set the SCP to $null.
3) Do you mean you want to add bbb.com and ccc.com to on-premises Exchange? Why do you want to add them to on-premise organization?
To add additional domains, you have to add accepted domains. For your reference: Accepted domains in Exchange Server.
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