Hi Bob,
I am an independent enthusiast.
Addressing to your query......
The provided information is not adequate for complete troubleshooting but you can surely give it a try for few things as below:
If error by any means states: "sender address is not valid" then you won't be able to add the member at all by any means.
If the user is genuine and internal then try the below approach:
If you want to add external users then try the below:
I hope and wish the approaches mentioned above will be insightful if they do not resolves your concern directly.