hi carllnglis,
the email address will not automatically be changed. it is decided by admin. when adding the domain2.co.uk, the admin will be asked if he wants to change user’s email address’ suffix to that domain. if he did that, the email address will be changed at that time. if he rejected, he can change user’s email address later manually in office 365 admin center by editing user’s details.
yes, we can as long as these two domains have been verified and have associated exchange online related dns records in office 365.
thanks,
iris