It's possible to get all the user sessions via PowerShell cmdlet. Maybe this helps.
import-module az
$subID = "xxxxxxxx"
$resgroup = "xxyz-rg"
$hostpoolName = "myHostpool"
Get-AzWvdUserSession -SubscriptionId $SubID -ResourceGroupName $resgroup -HostPoolName $hostpoolName | select Name, UserPrincipalName
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Regards
Andreas Baumgarten