Hi Jack
Which software are you using to make a bootable copy?
On my Mac, I have used Unetbootin to make bootable copies of Windows 10 on a USB. Have you given that a try?
You can download it from the following link:
UNetbootin - Homepage and Downloads
https://unetbootin.github.io/
Note: This is a non-Microsoft website. The page appears to be providing accurate, safe information. Watch out for ads on the site that may advertise products frequently classified as a PUP (Potentially Unwanted Products). Thoroughly research any product advertised on the site before you decide to download and install it.