@AnujHanda-4267
Per my test, we cannot create association between two identifiers.
As a workaround, I suggest you create a ID column filled in with same values in the Chtrobid column in the obChtrMaster table.
1.Select obChtrMaster content type -> Operations Designer View -> Choose obChtrMaster table -> New Association -> Choose ID column.
2.Go to a new web part page -> Add Business Date list by using Obspeedtech table -> Add Business Date related list by using obChtrMaster table.
Here's a reference video for you.
https://www.youtube.com/watch?v=Hg-FWy2kdW8
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