Hello José Luis Rando Calvo,
Thanks for your question.
It implies a seperate cost for the encryption/decryption operations happening through Azure Key Vault APIs.
See below for detailed pricing:
https://azure.microsoft.com/en-us/pricing/details/postgresql/server/
https://azure.microsoft.com/en-us/pricing/details/key-vault/
Please let me know if you have further questions
You can mark it 'Accept Answer' if this helped.