Microsoft 365 features that help users manage their subscriptions, account settings, and billing information.
Hi Fiona,
If the users are synced from AD, you need to manage them in AD. Admins cannot manage them in Office 365 Exchange Admin Center.
Generally, you need to check some points:
1. Make sure your default domain is your custom domain. (you have done it.)
2. Go to the proxyAddresses attribute, you should see some smtp address. You need to make the custom domain as capital letters.
For example: SMTP: ******@contoso.com,
not the smtp: ******@contoso.com
3. After that, please run force sync manually.
If the issue persists, can you provide some information?
1. A screenshot of AD proxyAddresses attribute.
2. Any errors in MIISClient?
3. One screenshot of the all email addresses in EAC for one problematic user like the example below.
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Best Regards,
Erick