Processes in Microsoft 365 for setting up Office apps, redeeming product keys, and activating licenses.
Pretty confident you're not going to need much support.
It's a relatively stand-alone process. Just need to download and install from your MS Account. In terms of Outlook, '365 is going to copy the profile used by '2010 and configure things accordingly - there won't be anything else you need to do.
Just a few really important things to know/remember
#1 - If you uninstall '2010 <after> installing '365, be sure to repair '365 via the <Control Panel>
#2 - If you do uninstall '2010 before installing '365, be sure to do via Control Panel and not the <Easy Fix> uninstall tool (in case someone tells you to do it that way) since that tool will also remove the Outlook profiles which means you'll have to reconfigure your email accounts. No reason to do that unless it's absolutely necessary (which shouldn't be the case).
At the end of the day, doubt that you'll find anything that will cause you to revert from '365 to '2010. Really similar so not much to get used to other then perhaps the color scheme for the Office ribbons.