A family of Microsoft word processing software products for creating web, email, and print documents.
Many Thanks for looking into it. (To summarise the below, knowing I should be able to use the font enabled me to locate and cure myissue).
The font was avalible for the user I was logged in as (and could be used on standard text). For good measure I uninstalled the font (first checking the file path), confirmed the file has been removed by checking the windows\fonts folder for the file using command prompt and dir, then reinstalled it for all users by selecting the .oft font file -> alternate click -> install for all users.
Again the font was avalible as a standard font, but not appearing as in the equation font dropdown and was not applied to equation objects when I had them highlighted and try to directly apply it, (Direct formatting does work with the other maths fonts).
So, next up I created a new local user with admin privileges. The font appeared in the equation font dropdown box for that new user (The others did not as they were not installed for all users).
I re-logged on to my account, removed all the other Math fonts exept Cambria math. Reloaded Word, the font was still not appearing as an equation font.
I've previously experiemented with converting with converting the otf to a ttf to enable Word to correctly embed it in pdf files (Rather than as a bitmap as previous posters have had issues with). Although I'm reinstalling the OTF from a new download, it now occured to me it's possible that Word has cached some information somewhere that this font is a standard font not a math font, Maybe a registry entry which isn't removed when the font in uninstalled...
*Disclaimer - Manual eding of the registry can break your computer!*
Sure enough searching on a few choice terms I find the following section of the registry Computer\HKEY_CURRENT_USER\Software\Microsoft\Office\16.0\Common\MathFonts with an entry for Latin Modern Math set to 0 while fonts such as Cambria Math had the value 1, setting it to 1 for Latin Modern Math seems to resolve my issue.
Thanks again for confirming that it should work, that set me down the right path for fixing it :)