A family of Microsoft relational database management systems designed for ease of use.
Sorry but this is the message I get when I try to do the indexing.
My guess would be that you have indexed one or both of the columns individually, not both columns as a pair in a single index. If you follow the description I gave in my last reply of how to create a unique index on two columns you should be able to achieve your aim.
On the subject of constraints in general, you might like to take a look at Constraints.zip in my public databases folder at:
https://onedrive.live.com/?cid=44CC60D7FEA42912&id=44CC60D7FEA42912!169
This little demo file illustrates how database constraints can be applied through normalization of the tables, indexing and by the application of a CHECK CONSTRAINT to a table.