A family of Microsoft word processing software products for creating web, email, and print documents.
Doug has told you how to remove the page numbers. For more on formatting the TOC, see http://wordfaqs.ssbarnhill.com/TOCTips.htm#Appearance
Changing the alignment of any one of the TOC entries should update the paragraph style for that level because TOC styles are by default set to update automatically. For example, if a Level 1 heading is centered, the TOC 1 style will be updated. It should not be necessary to center or recenter the entire TOC.