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Hi there,
I'm not the original poster, but am experiencing the same issue and wanted to share answers to your questions based on troubleshooting done by our team:
a. Does the problem happens with a specific PDF file or any PDF file? Any PDF file.
b. If the same PDF file is uploaded to a different Document Library or another SharePoint Online site, can the PDF be previewed? We have found that this same file will require re-uploading to the SharePoint site and on the 4th or 5th attempt, the file is successfully uploaded. Until then, it will continue to show invalid. We are currently using the info button within the folder to see if the Preview displays. If the preview does not display, it means that the PDF needs to be re-uploaded.
c. Do other users who can access the site also encounter the same behavior? Yes.
d**. Can the user preview or open the Office files without any problem?** No. The issue impacts all users after the PDF is uploaded. Local files are still accessible and no issue.
Originally, I thought this issue was tied to one user but it is actually non-descript and is impacting multiple users at different frequencies. This issue has been prevalent since early July, but we're just now noticing it as we are beginning to access and reference these PDF files and now have to retrace our steps.