A family of Microsoft presentation graphics products that offer tools for creating presentations and adding graphic effects like multimedia objects and special effects with text.
I spent quite a while looking into this today: there isn't a way to edit this data conventionally from within Powerpoint absent some kind of extension, because it delegates all that to Excel. However, it is editable. People often suggest that the semantic data is lost when a chart is unlinked, but this isn't exactly true: you can verify that if you change the chart type, the data is reflowed logically. I haven't found the answer anywhere else, so so in the hope of saving others some time, here is what you can do if you don't mind getting your hands dirty.
The short answer is that if you rename your .PPTX file to ,ZIP, you can browse it as an archive. Inside, the display semantics for unlinked charts are stored at /ppt/charts/chart1.xml, chart2.xml, etc. (You'll have to figure which is which, though you can generally tell by inspecting them.) Data series are stored in c:ser tags, with the values in c:v tags. These are the main things you'll likely need to edit, as the rest is mostly editable from PPT even when unlinked.
If you want to do something complicated, the specifications for these XML files are a part of the Office Open XML specification, which you should be able to find around. For instance here is the spec for a bar chart series, and Microsoft's API for the same thing is here. Unfortunately, the official API for this is in C#, with all the overhead that implies; I don't believe it's possible to do this with the normal VBA document structure. If you don't mind an ugly solution though, you can use VBA to unzip the PPTX, edit the XML manually using MSXML, and then put it back together. This library automates some of this, though I haven't tried it myself, and it should be possible to do the same in pure PowerShell.