A family of Microsoft word processing software products for creating web, email, and print documents.
Just so you understand, there is no existing template for what you want. People here may be able to help you create one, though.
To do that, we would need to have a much better understanding of your design criteria.
I suspect you mean one that will create a document that has a TOC cover page and the equivalent of loose-leaf binder tabs either on the side or on the bottom of every page.