Hi SL Robbins, thank you for you reply.
To better assist you, when you encounter the "Office Store not available" prompt in PowerPoint, are there any other prompts?
In fact, it's not an uncommon occurrence to encounter Office Store unavailability when adding add-ins, and this is usually due to the fact that the user is using Microsoft 365, which is provided by their organization, and the administrators of the organization have disabled the feature to add add-ins to Microsoft 365 apps.
In your post, you mentioned that you are using Microsoft 365 Personal, but to be on the safe side, it would be a good idea to check your current Microsoft 365 license version, and if you find that you are currently using a company or organization-provided account, then you will need to either switch to your personal account, or contact your organization's administrator to change the relevant permission settings.
If you continue to experience this issue with your personal subscription, please provide us with more specific information, and it would be helpful if you could provide us with a full screenshot of your edition page and the page that says "Office Store is not available".
Looking forward to your further reply.
Best Regards
Eliac | Microsoft Community Support Specialist