Hi as you have seen Get-Ummailbox lists all the UM Mailboxes
If you want to see which are being used then use:
https://learn.microsoft.com/en-us/powershell/module/exchange/get-umcalldatarecord?view=exchange-ps
Get-UMCallDataRecord
This will list all the active calls by user
$MBX = get-mailbox -resultsize unlimited
$MBX |% { Get-UMCallDataRecord -Mailbox $_.Name}
You can output to a csv etc...