Hello Emma4444
Good morning to you and thank you for your post in the Microsoft community.
I read your thread and got some background information from your scenario. After conducting some research, I found that encrypt emails on Microsoft business standard is possible
Before suggesting you some troubleshooting steps may I know which outlook version currently, you're using? is that classic outlook or new outlook?
For new outlook please follow the bellow:
Encrypt a message with Microsoft Purview Message Encryption in new Outlook Send S/MIME and Microsoft Purview encrypted emails in Outlook - Microsoft Support
Microsoft Purview Message Encryption with IRM protection should not be applied to a message that is already signed or encrypted using S/MIME. Instead, to apply IRM protection, S/MIME signature and encryption must be removed from the message (see above). The same applies for IRM-protected messages; you should not sign or encrypt them using S/MIME.
**Note:**New Outlook supports Microsoft 365 Message Encryption as long as your email server has an Office 365 Enterprise E3 license. If not, you can encrypt messages using S/MIME.
- In an email message, choose Options, and then select Encrypt.
- Pick the encryption that has the restrictions you want to enforce, such as Encrypt or Do Not Forward.

- Finish composing your email and then select Send.
If you have any Update or I misunderstood, you please feel free to let me know. I will continue to assist you. Your understanding and co-operation are highly appreciated.
Thanks for your precious time. Have a nice day!
Sincerely
Shajia Afrin | Community Moderator