Hello,
I am sorry for your loss.
I wish I could share good news, but the truth is no one can get you the bitlocker key, including Microsoft staff/support.
Typically by default, bitlocker is associated with the Microsoft account used during encryption. But you need to know the account credential to sign into here. https://account.microsoft.com/devices/recoverykey
Otherwise, it can be associated with his work account if he has set it up on his computer while encryption was implemtened on the drive, Then sign into https://aka.ms/aadrecoverykey and you need to know his work account credential.
There's also a chance he might have written it down somewhere or saved it as a local file and stored somewhere.
But regardless, Microsoft is not able to support bitlocker manually: https://support.microsoft.com/en-us/windows/find-your-bitlocker-recovery-key-6b71ad27-0b89-ea08-f143-056f5ab347d6