Hi Dale 76118,
once you have deployed a new KMS host with your KMS keys, the endpoints that were previously activated with MAK keys will continue to use those MAK keys unless you force them to use the KMS keys. The endpoints will not automatically detect the KMS host in AD/DNS and start using the KMS keys.
Regarding the Win 10 workstations that may not communicate with AD beyond 180 days, if a new workstation is assigned a KMS key via ADBA and does not communicate with AD, it will become unlicensed after 180 days. To avoid this, you can configure the workstation to communicate with the KMS host at least once every 180 days to maintain activation.
Hope it helps.