Hi Ryan Saitta,
You can create folders on the second hard drive (E drive), add the folders to the libraries like documents, music, pictures and videos and thus save files to them making it a default location.
Also you can change the location of the folders my pictures, my music, etc. Follow the below steps and check-
a. Go to the location C:\Users\ (user name).
b. Now right click the folder whose location you want to change like my pictures, my music, etc.
c. Now click on the location tab and change the location under the heading “you can change where files in this folder are stored to another place on this hard drive, another driver or another computer on the network”.
d. Now click Apply and Ok.
Actually libraries (like pictures library) are where you go to manage your documents, music, pictures, and other files. You can browse your files the same way you would in a folder or you can view your files arranged by properties like date, type, and author.
In some ways, a library is similar to a folder. For example, when you open a library, you'll see one or more files. However, unlike a folder, a library gathers files that are stored in several locations. This is a subtle, but important, difference.Libraries don't actually store your items. They monitor folders that contain your items, and let you access and arrange the items in different ways. For instance, if you have document files in folders on your hard disk and on an external drive, you can access all of your document files at once using the Document library.
You may refer to the below links for details -
http://windows.microsoft.com/en-us/windows7/Working-with-libraries
http://windows.microsoft.com/en-US/windows7/Create-a-new-library
http://windows.microsoft.com/en-US/windows7/Include-folders-in-a-library
http://windows.microsoft.com/en-us/windows7/Libraries-frequently-asked-questions
Hope this helps.
Thanks,
Meghmala – Microsoft Support
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