You could expedite things by expanding on the description of the methods you used to try to fix your computer and what happened.
I suspect that your pci.sys file may have been deleted or quarantined by your antivirus software. Maybe it was really afflicted, but some scanning softwares will delete critical XP system files resulting in a no boot scenario (we'll call it an accident).
Describe your current antivirus and anti malware situation: McAfee, Norton, Spybot, AVG, Avira!, MSE, Defender, ZoneAlarm, PC Tools, Comodo, etc.
Forunately, there are several copies of the pci.sys file on your HDD in other places - you just have to boot on something to replace the missing file, then get rid of your afflicted antiwhatever software, consider something more friendly, use some different scanning software, then fix any remaining issues.
Your system has a CD/DVD drive, so create a bootable XP Recovery Console CD and boot on that, then we can replace the missing file.
You can make a bootable Recovery Console CD by downloading an ISO file and burning it to a CD.
The bootable ISO image file you need to download is called:
xp_rec_con.iso
Download the ISO file from here:
http://www.mediafire.com/?ueyyzfymmig
Use this free and easy program to create your bootable CD:
Here are some instructions for ImgBurn:
http://forum.imgburn.com/index.php?showtopic=611
It would be a good idea to test your bootable CD on a computer that is working.
You may need to adjust the computer BIOS settings to use the CD ROM drive as the first boot device instead of the hard disk. These adjustments are
made before Windows tries to load. If you miss it, you will have to reboot the system again.
When you boot on the CD, follow the prompts:
Press any key to boot from CD...
The Windows Setup... will proceed.
Press 'R' to enter the Recovery Console.
Select the installation you want to access (usually 1: C:\WINDOWS)
You may be asked to enter the Administrator password (usually empty).
You should be in the C:\WINDOWS folder. This is the same as the C:\WINDOWS folder you see in explorer.
When you get this part going, reply back and you can proceed.
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