This depends on PC maker's utilities but you don't say what type of PC you have.
For Dells & possibly others, go to
1 Control panel, Windows mobility center - There may be an item called Function key row with a dropdown list. You should find it set to Multimedia keys & can select Function keys instead. The settigs will revert to their default when you restart the PC.
2 Reboot into the BIOS & look for the Multimedia key item. Changing this to Function keys instead will change the default behaviour.
If your PC does not provide for these changes then you'll have to go to the PC maker's support site to find out how to do it.