Hi Anupam,
Thank you for visiting Microsoft Community.
As per the issue description and the error code which you are getting while running "slmgr//ato" command, it seems that you are having issue in activating your Windows.
Use of slmgr//ato command:
For retail editions and volume systems with a KMS host key or a Multiple Activation Key (MAK) installed, /ato prompts Windows to attempt online activation. Activate Windows license and product key against Microsoft's server.
If you are getting error code 0x80072EF7 then I would suggest you to try the steps provided in the article provided below and see if it helps you to fix the issue.
Error 0x8007232b or 0x8007007B occurs when you try to activate Windows
Note: This section, method, or task contains steps that tell you how to modify the registry. However, serious problems might occur if you modify the registry incorrectly. Therefore, make sure that you follow these steps carefully. For added protection, back up the registry before you modify it. Then, you can restore the registry if a problem occurs. For more information about how to back up and restore the registry, click the following article number to view the article in the Microsoft Knowledge Base:
You can use the following link in order to back up and restore the registry in Windows:http://support.microsoft.com/kb/322756/
Hope this would help. If issue still persists post back with current status of your computer and result of the proposed suggestion, we will be happy to assist you.
Regards,