Are you saying that the option to reset the file type association in Settings is missing on your PC? The button should be under Settings > Apps > Default apps. Clicking Reset should revert back all of the file association to default.
If this is the case, you can try creating a new user account and then check the default app for the PUP file type. A new user account will have a default configuration. Therefore, you can download the PUP file on the new user account to figure out the default app and then switch back to your main account to modify the default app configuration. Check this link for the steps on how to create a user account in Windows 10.
Let me know if you need further assistance.