- Open Notepad > File > Save As > Put a name in File Name: box with extension.exe (example - temp.exe) and change Save As type: to all files and OK
- Now right click on the file whose association do you want to change or remove > Open with > Choose another app > Scroll down > More apps > Look for another app on this PC > Choose the .exe file of step 1 > OK
Now delete the .exe file of step 1.
This will cause the association to be broken.
Credit - DaveM121