There is no "failover mode" per se.
One Server is the "production" server that handles syncs and exports and you can have other servers in Staging mode, ready to be switched to the "primary"
All of these servers should be treated as peers. In other words, configured the same and can be set as the "primary" server whenever needed , DR or during upgrades.
https://learn.microsoft.com/en-us/azure/active-directory/hybrid/how-to-connect-sync-staging-server
Best practice is to have at least two AADConnect servers to accomplish this.