Hi Havel,
You won't see the specific IPs for those two devices but what you need to look for is the Network Destination which covers them.
For example, if you run the "ipconfig" command and your IP address is 192.168.0.10 and Subnet Mask is 255.255.255.0 then in the route print output you're looking for the Network Destination of 192.168.0.0 with Netmask 255.255.255.0 as this covers all the devices on your local network.
For your computer to connect to the printer and Xbox the Gateway for that Network Destination should be "on-link" and Interface be your IP address, so I would recommend to compare the two outputs and see if the Gateway and Interface values change when you connect/disconnect the VPN.
If they do then check through the settings of the VPN software for anything relating to accessing resources on your local network, as the VPN shouldn't be changing the Gateway for local IP addresses only for internet addresses.