Hi MC,
I am Sumit, an Independent Advisor and a 3 year Windows Insider MVP here to help.
Natively 2FA isn't supported in Windows. The best way is to use Windows Hello Fingerprint which would only log you in when the fingerprint matches. This is the best security method available.
Another alternate is using a Booting Password in BIOS Settings. It would ask for a password every time you start your PC in addition to Windows login.
For suggestions, feel free to write it in Feedback Hub.