Hi, I am Van. I'll be glad to assist you today.
You can try blocking the app by creating a firewall rule. Open the Windows defender then go to Firewall & Network protection > Advanced settings. In the Firewall advanced settings, click the Outbound rules then click New Rule in the right pane.
In the New Outbound Rule Wizard, select Program then click next. In the next screen, select This program path then browse the steam app (C:\Program Files (x86)\Steam) then click next. In the next screen, select Block the connection. Apply it to all connection type (Domain, Private, Public) then click next. Name the rule you created then click finish.
Open steam and check if the firewall blocks the app connection.
Best regards,
Van