Hi Dhanam.... thanks for your prompt reply. I'm going to look silly now, but in the interests of honesty, unfortunately I must. It was working all along, but I couldn't see it. The problem was that I had the orientation of the monitors in Display Settings wrong. So when I moved my mouse to the left to go onto the secondary monitor, it wasn't going any further than the left edge of the Primary one.. When I moved it to the right, it appeared on the second. So I had 1 and 2 the wrong way around. The reason I didn't think it was being detected, was because it had already detected the second one..... it was as though I was asking it to detect a third one, which wasn't there. Hope that all makes sense, and I apologise for wasting your time.
Many thanks again for your quick reply and helpful advice....
Steve