I actually found a solution to this question, believe me or not. I didn't involve using the Microsoft Creation tool, however.
I was able to download and install Rufus, which was able to create a bootable drive from the SD card in the SD card slot of my laptop. I was also able to test it by changing the boot order, temporarily, through the BIOS, to the SD card, in which this worked fairly well, in that it was able to boot up in a fresh windows 11 OS environment! My goal, here, was, instead of creating an image of the SDD installed on board of my device, I wanted to have a known-good OS on standby in the event something catastrophic were to happen. (Though rare, it's possible. All other data is backed up via iCloud and OneDrive cloud storages, so I really wouldn't need to have a full file-directory backup with all installed applications etc...)
But either way, my problem is solved. Thanks for the input and feedback on my original inquiry :)