Hi,
I'm Rodrigo and I'll help you.
Some applications don't start from the startup folder, I'm not sure why but this workaround works for those applications:
Create a shortcut to launch a Command Prompt that will launch the application.
Right click in a blank area of the desktop > New > Shortcut > Paste the command below on the location box:
C:\Windows\System32\cmd.exe /c start "" "Path"
Change Path with the application path, for example:
C:\Windows\System32\cmd.exe /c start "" "C:\Program Files (x86)\Microsoft\Edge\Application\msedge.exe"
Next > Name the shortcut > Finish > Test the shortcut, if it works as expected, copy to the shell:startup folder.