Hello Yung Kit,
How are you? I am interested in this case, can I know if everything works well now? If you still can't send messages to your owned Office 365 Group via your Hotmail account, please try
to send any message from any other personal mail account, like Outlook.com, Gmail.com, or Yahoo.com. If issue persists with the same error message?
Meanwhile, in some cases, the autocompleted "To" address can cause this kind issue, so you may need to remove that cached group's email address from the autocompleted list then typed its
email address manually in the "To" field.
If everything works well, we are really glad to hear it. And if possible, we also welcome you share the solution with us here to benefit other community members. Thanks for your time.
Happy new year.
Cheers,
Rudy