Hi Eric D Csehoski,
Thanks for posting in our forum. I'm here to help.
As far as l know, generally, If someone receives emails with an SMIME.ps7 attachment in the email, that may means the sender has an Email Signing certificate installed on their computer. Please check whether you have digitally sign individual messages. If so, please remove and re-add the signature and check if it helps.
On the other hand, to check whether to issue is related to add-ins in Outlook, please kindly contact the user to open Outlook in safe mode to see if the problem persists. If not, please open Outlook normally and temporarily disable add-ins one at a time to see which one might have caused the problem.
In addition, to further check if it is related to the current Outlook profile you add your account to, please kindly switch to a new profile and only add the affected account here to see if the problem persists.
Hope it helps. Please feel free to let us know if there are any updates from you. If the issue persists, please provide us the screenshot of the email user received and the intact screenshot of the users’ Outlook version for further analysis. Thanks for your time and cooperation.
Best Regards
Nerissa