A family of Microsoft presentation graphics products that offer tools for creating presentations and adding graphic effects like multimedia objects and special effects with text.
This typically happens when you download a PPTX file using Internet Explorer version 7 and above. It mistakenly downloads the file as a ZIP file instead of PPTX. When downloading such a file with such a browser, be sure to manually change the extension to "PPTX".
Having said that, with any PPTX, you can "unzip" it, but there's no real value in doing so. A PPTX file is the new format which technically is a zipped file of folders and files. But for your purposes, you should be able to simply open a PPTX file in PowerPoint without any unzipping.
Also, besides the fix above, you can 1) use a different browser or a pre-version 7 IE browser, or 2) have your network admins update the MIME definitions on the server from where you downloaded the file. (Have them read this: http://msdn.microsoft.com/en-us/library/ms775148%28v=VS.85%29.aspx.)
-Mel