A family of Microsoft spreadsheet software with tools for analyzing, charting, and communicating data.
RSD is just the sample standard deviation divided by the expected value of the sample, so
RSD = STDEV(rng)/AVERAGE(rng)
formatted as a percentage or
RSD = 100 * STDEV(rng)/AVEREAGE(rng)
when formatted as a number.
I don't remember any version of XL actually combining the two into a single function - there's hardly any point...
Note that in XL2011, STDEV() is deprecated, so the preferred formula is
=STDEV.S(rng)/AVERAGE(rng)
but the first will still work.