A family of Microsoft presentation graphics products that offer tools for creating presentations and adding graphic effects like multimedia objects and special effects with text.
You may have an easier time of it if you design the label in PPT (for just the reasons you mention) then copy/paste the entire label design into a Word document for printing to Avery labels.
If you happen to have Corel Draw, I'd use that rather than Word; it's fairly straightforward to print multiple labels per sheet from Draw.
You could also check http://www.avery.com
They have some kind of online label printing feature; I haven't tried it, but I'm guessing you could create your graphic in PPT, save as an image or other graphics file format, then upload to the avery site for printing.