Apologies for late response here! You may want to know that App Service app runs in an App Service plan, and App Service plans are deployed into one of the deployment units called as webspace. Each deployment unit is assigned a set of virtual IP addresses, which includes one public inbound IP address and a set of outbound IP addresses.
But if you scale your app between tier, one or more of the four outbound IP addresses may change (with some of the additional outbound IP addresses)
Check: When outbound IPs change
If you are looking for that your App Service is use a fixed IP address then for static outbound IP you can use Azure NAT Gateway and static inbound IP you may use Application gateway.
Refer to this detail blog How to use static IP addresses with Azure App Service