Hi @Andy ,
You want to enter users from another domain in the list person column.
1.You need to first establish a trust relationship between the two domains. Then Configure People Picker in SharePoint 2019.
For How to Add Trust Domains in a SharePoint Farm , please refer to: https://www.boostsolutions.com/blog/how-to-add-trust-domains-in-a-sharepoint-farm/
Note: Microsoft is providing this information as a convenience to you. The sites are not controlled by Microsoft. Microsoft cannot make any representations regarding the quality, safety, or suitability of any software or information found there. Please make sure that you completely understand the risk before retrieving any suggestions from the above link.
2.Then run the following command for each of your web applications, substituting the example URL and domains with your web application URL, local and trusted domain and/or forest.For a full forest trust:
stsadm -o setproperty -pn peoplepicker-searchadforests -pv "forest:MY-DOMAIN.local;forest:TRUSTED-DOMAIN.local;domain:MY-DOMAIN.local;domain:TRUSTED-DOMAIN.local" -url http://my-sp-site.com.au/
You should now be able to add users from both sides of the trust to your Sharepoint list.
If the answer is helpful, please click "Accept Answer" and kindly upvote it. If you have extra questions about this answer, please click "Comment".
Note: Please follow the steps in our documentation to enable e-mail notifications if you want to receive the related email notification for this thread.