Hi @sns ,
Answers to your questions:
- You need to run product config wizard in all servers.
- Run the Product Config wizard on the 1st app server where you want host the Central admin,then run Config Wizard on all other servers and join them to the farm.
I found a case similar to yours: https://sharepoint.stackexchange.com/questions/136303/multi-server-sharepoint-farm-setup - You need to run Upgrade Content Database before running the Product Configuration Wizard.
Reference: https://learn.microsoft.com/en-us/sharepoint/troubleshoot/administration/upgrade-available-status-in-new-farm
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