Hi JuanPerez-1223,
This is in reference to BitLocker Recovery.
Startup Key file
Startup Key file is a key file you would save on a USB drive/removable media to start Windows computer without having to enter the BitLocker recovery or password. An encryption key that can be stored on most removable media. This key protector can be used alone on non-TPM computers, or with a TPM for added security.
Please refer a below mentioned article for a detailed information.
Prepare the organization for BitLocker Planning and policies (Windows 10) | Microsoft Learn
BitLocker Recovery Key
Your BitLocker recovery key is a unique 48-digit numerical password that can be used to unlock your system if BitLocker is otherwise unable to confirm for certain that the attempt to access the system drive is authorized.
Please refer a below mentioned article for a detailed information.
Finding your BitLocker recovery key in Windows - Microsoft Support
Regards,
CK