Hi @Roger Roger,
The Trustee parameter of Add-RecipientPermission can only add one user at a time.
If you want to grant the send as permission to multiple users, you can refer to the following to create a CSV file:
$UserList = Import-CSV C:\temp\users.csv
ForEach ($User in $UserList) {
Add-RecipientPermission distributiongroup -AccessRights SendAs –Trustee $user.alias
}
The Add-ADPermission command is the same as Add-RecipientPermission.
In addition ,I found this document for you reference:
Permissions in Exchange hybrid deployments | Microsoft Learn
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