Hello Michael,
Hope you are doing well today!
No, it is not possible to set a unique key constraint on an array in Cosmos DB in Azure. In Cosmos DB, unique key constraints can only be set on individual fields and not arrays. If you need to enforce uniqueness for array values, you can add a field to store a hash of the array and set a unique key constraint on the hash field. I hope this answers your query.
Regards,
Umang Middha