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You can do it via registry (with elevated privileges) HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\Windows NT\CurrentVersion\ProfileList
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Windows 10
On Domain
You can do it via registry (with elevated privileges) HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\Windows NT\CurrentVersion\ProfileList
This link may be useful:
https://www.tenforums.com/tutorials/89060-change-name-user-profile-folder-windows-10-a.html