Hi @KAI SENG ,
Regarding the error message in the screenshot you shared, do you have any impression on the database mentioned in the error? Based on my research, "first storage group" appears to be related to some outdated version of Exchange server, so I am wondering if there was an earlier version of Exchange in your environment.
Besides, could you run the command below to check the arbitration mailboxes in the environment? Make sure the databases returned in the output are all mounted properly.
Set-ADServerSettings -ViewEntireForest $true; Get-Mailbox -Arbitration | Format-Table Name, ServerName, Database, AdminDisplayVersion
Furthermore, in order to narrow down if it's an issue with the administrator account, please try testing with a different admin account and see how it goes.
You can also try migrating mailboxes using the New-MoveRequest cmdlet and check the result:
New-MoveRequest -Identity '******@contoso.com' -TargetDatabase "DB01"
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