William Beglen Thanks for posting your question in Microsoft Q&A. Yes, you need to mount file share before accessing it. Currently, Mount file shares are only supported for Linux Web Apps (and Windows Container Web apps), and you can follow doc: Mount file shares in setting the mount via CLI az webapp config storage-account add
(or PowerShell command).
Then you can use System.IO to access files with the mount-path and I found article https://www.serverlessnotes.com/docs/mounting-file-shares-on-linux-azure-function-apps created by MVP that would help with your scenario. Also, .NET SDK can be used to access file shares as described in Access the file share programmatically (after setting up Configure Azure Storage connection strings). I hope this helps with your question and let me know if you have any questions or face issues.
If you found the answer to your question helpful, please take a moment to mark it as "Yes" for others to benefit from your experience. Or simply add a comment tagging me and would be happy to answer your questions.