Hello,
When using DHCP, you cannot manually add multiple IP addresses to a single network interface from within the Windows operating system. DHCP automatically assigns IP addresses to the NIC, and you won't be able to add additional IP addresses manually.
Can I deploy a DHCP server in a VNet?
Azure VNets provide DHCP service and DNS to VMs and client/server DHCP (source port UDP/68, destination port UDP/67) not supported in a VNet. You cannot deploy your own DHCP service to receive and provide unicast/broadcast client/server DHCP traffic for endpoints inside a VNet. It is also an unsupported scenario to deploy a DHCP server VM with the intent to receive unicast DHCP relay (source port UDP/67, destination port UDP/67) DHCP traffic.
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