Hi Jonathan Prom Scharff •,
Welcome to Microsoft Q&A forum and thanks for using Azure Services.
As I understand, you want to use pgvector extension in Azure Database for PostgreSQL.
Could you please open Azure Database for PostgreSQL flexible server-> Server Parameters-> Search for azure.extensions -> Enable Vector as shown below:
Please try and let us know if you face any issue.
If not able to perform, please share us the configuration details of the flexible server so that we can further investigate.
Thank you.